A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide pi-donor ancillary ligand.

نویسندگان

  • Winfried P Kretschmer
  • Chris Dijkhuis
  • Auke Meetsma
  • Bart Hessen
  • Jan H Teuben
چکیده

The titanium complex Cp[1,3-(2',6'-Me2C6H3)2(CH2N)2C=N]Ti(CH2Ph)2, with a monoanionic eta 1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.

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عنوان ژورنال:
  • Chemical communications

دوره 6  شماره 

صفحات  -

تاریخ انتشار 2002